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| You are here : 4everlast.de ----> SAFETY-M.S.D.S. ----> SUPERPRIMER |
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11/28/08
MATERIAL SAFETY DATA SHEET Page 01 of 06
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| M A T E R I A L S A F E T Y D A T A S H E E T |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : SUPERPRIMER
IDENTIFICATION NUMBER: 35675
PRODUCT USE/CLASS : Adhesion Promoter
EU and WORLDWIDE 24 hr emergency contact :
Paul Bruns GmbH, Germany
Phone +49 40 54 77 850
Fax +49 40 54 77 8520
PREPARER: Safety Health & Regulatory Affairs PREPARE DATE: 11/28/08
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
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01 Hexylacetate 88230-35-7 40.0-45.0
02 Polyurethane Resin ----- 50.0
ITEM ------------ CHEMICAL NAME ------------- EC Risk Phrases
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01 Hexylacetate R 10
02 Polyurethane Resin ----
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: This health hazard information is based on information
on similar products.
Low toxicity under normal conditions of handling and use.
MATERIAL SAFETY DATA SHEET Page 02 of 06
Item No.: 35675
ACUTE EFFECTS - EYE CONTACT: Contact may cause injury to eye tissue if not
removed promptly.
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| SECTION 3 - HAZARDS IDENTIFICATION |
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ACUTE EFFECTS - SKIN CONTACT: . Prolonged skin contact may cause dermatitis.
ACUTE EFFECTS - INHALATION: Vapors and/or aerosols which may be formed at
elevated temperatures may be irritating.
ACUTE EFFECTS - INGESTION:Ingestion may cause fatigue, muscular weakness,
labored breathing. Ingestion of significant amounts may cause kidney damage.
CHRONIC OVEREXPOSURE EFFECTS: N.A.
OTHER INFORMATION: HMSIS Hazard Ratings: Health-1,Flammability-1,
Chemical Reaktivity-0
NFPA Hazard Ratings : Health-1,Flammability-1,
Instability-0
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and
water. Get medical attention if symptons occur.
INHALATION: If symptoms occur, remove to fresh air. Medical personnel may
administer oxygen if breathing is difficult. Seek medical attention if
symptoms persist.
INGESTION: Swallowing less than an ounce will not cause significant harm.
MATERIAL SAFETY DATA SHEET Page 03 of 06
Item No.: 35675
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 39 Celsius 102 F LOWER EXPLOSIVE LIMIT: N.A.
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: 430 Celsius 790 F
EXTINGUISHING MEDIA: USE DRY MATERIALS(EX.:SAND)
OR CLASS D EXSTINGUISHING AGENT
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Collect large
spills mechanically or with liuid absorb material and transfer waste to a
leakproof container.Remove all sources of ignition. Don´t use a vakuum
cleaner. Material cures on air contact to solid resin.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Follow all MSDS/label precautions even after container is
emptied because it may retain product residues. FOR INDUSTRIAL USE ONLY.
STORAGE: KEEP OUT OF THE REACH OF CHILDREN.
MATERIAL SAFETY DATA SHEET Page 04 of 06
Item No.: 35675
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: General ventilation usually adequate. Local exhaust
as needed to control vapor or dust levels to below lowest component TLV.
RESPIRATORY PROTECTION: None normally required under general ventilation.
If TLV/PEL is exceeded, if use is performed in a poorly-ventilated space,
or if inhalation effects occur, use NIOSH-approved vapor cartridge
respirator in accordance with applicable health and safety regulations and
manufacturer's recommendations.
SKIN PROTECTION: Clean clothing to cover skin. Saranex gloves. Butyl
rubber gloves. Neoprene gloves. Nitrile gloves. PVA gloves.
EYE PROTECTION: Chemical splash goggles.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use. DO NOT reuse empty containers
without commercial clean or recondition. Follow all MSDS/label precautions
even after container is emptied.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : (305F)150Celsius VAPOR DENSITY : Is heavier than air
ODOR : Mild ester ODOR THRESHOLD : No data
APPEARANCE : slightly yellow EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Negligible Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 1.020
VAPOR PRESSURE : No data pH @ 0.0 % : N/A
PHYSICAL STATE : Liquid VISCOSITY : medium
FLASH POINT : 39 deg Celsius , 102 deg Fahrenheit
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Keep away from strong oxidizing agents.
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
MATERIAL SAFETY DATA SHEET Page 05 of 06
Item No.: 35675
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Various hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Hexylacetate Oral-rat 60.0 g/kg 70 g/kg (Mouse)
Polyurethane Resin Not Applicable Not Applicable
This health hazard assessment is based on information available on similar
products.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: Not Applicable.
The product is essentially insoluble in water. WGK 1 (self classification)
The product is anticipated to be partially removed in biological treatment
processes.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD:dispose material in accordance with local, state and
federal regulations.
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| TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: RESIN SOLUTION U.N. No. 1866
DOT TECHNICAL NAME: Coating Solution
DOT HAZARD CLASS: N/A HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE:
INTERNATIONAL SHIPPING NAME: Resin Solution U.N. No. 1866
INTERNATIONAL ID NUMBER: 3.3/1866/III
IMDG CLASS (1Û,2Û): N/A IMDG PAGE NUMBER: 330
IMDG EMS: 3.05 IATA CLASS (1Û,2Û): N/A
MFAG 310
ADR ITEM NO.: 3/31C ADR TREMCARD: 3/31C
SUPPLEMENTAL INFORMATION: Not Applicable.
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| SECTION 15 - REGULATORY INFORMATION |
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EEC classification according to EEC-rules:
HAZARD SYMBOL :-
RISK PHRASES : R 10 (flammable)
Safety phrases : S7/8 ( keep container tightly closed and dry )
S3/4/49 ( Only store in original container in a cool, well
ventilated place )
CALIFORNIA PROPOSITION 65:
WARNING: This product contains no chemical(s) known to the State of
California to cause cancer.
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
COMPONENT RCRA CLASSIFICATIONS: Not regulated
COMPONENT RCRA CODES: Not Applicable.
MATERIAL SAFETY DATA SHEET Page 06 of 06
Item No.: 35675
CERCLA RQ VALUE (MINIMUM): None known
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: -
REASON FOR REVISION: new format
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
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The information contained in this MSDS was obtained from current and reliable sources, however, the
data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy.
Since the conditions or handling, storage and disposal of this product are beyond the control of
the manufacturer will not be responsible
for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred,
regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS.
Various government agencies may have specific regulations regarding the transportation, handling,
storage, use, or disposal of this product which may not be covered by this MSDS.
The user is responsible for full compliance.